Issue 22, 1988

Carbon–hydrogen activation chemistry: hydroxylation of C2, C3, and cyclo-C6 hydrocarbons by manganese cluster catalysts with a mono-oxygen transfer reagent

Abstract

Manganese clusters, Mn3–4O1–2LxLy(Lx= RCO2; Ly= pyridine or 2,2′-bipyridine), are novel catalysts that can convert C–H bonds to C–OH bonds in C2, C3, and cyclo-C6 hydrocarbons in the presence of t-butyl hydroperoxide as the mono-oxygen transfer reagent.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1504-1506

Carbon–hydrogen activation chemistry: hydroxylation of C2, C3, and cyclo-C6 hydrocarbons by manganese cluster catalysts with a mono-oxygen transfer reagent

R. H. Fish, R. H. Fong, J. B. Vincent and G. Christou, J. Chem. Soc., Chem. Commun., 1988, 1504 DOI: 10.1039/C39880001504

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