Stereospecific and regiospecific metal–ligand hydrogen migration reactions have been observed for the new complexes [(azul)M2H(CO)5L]+(azul = azulene or guaiazulene) together with a regiospecific low temperature photochemical substitution reaction of (azul)Mo2(CO)6 to give (azul)Mo2(CO)5L.
K. E. Clode and A. H. Wright, J. Chem. Soc., Chem. Commun., 1988, 1463 DOI: 10.1039/C39880001463
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