Decarboxylation of the O-methyl, O-p-cresyl and O-3β-cholestanyl glycosides of 3-deoxy-4,5,7-tri-O-benzyl-D-arabino-heptulosonic acid by means of the derived O-acyl thiohydroxamates leads stereoselectively to the corresponding 2-deoxy-β-D-glucosides.
D. Crich and T. J. Ritchie, J. Chem. Soc., Chem. Commun., 1988, 1461 DOI: 10.1039/C39880001461
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