A mononuclear trigonal bipyramidal vanadium(III) complex, [V(tipt)3(thf)2](tipt = 2,4,6-tri-isopropylbenzenethiolate; thf = tetrahydrofuran), has been prepared and characterized by X-ray crystallography and magnetic susceptibility, u.v.–visible and infrared spectroscopic, and electrochemical measurements.
C. R. Randall and W. H. Armstrong, J. Chem. Soc., Chem. Commun., 1988, 986 DOI: 10.1039/C39880000986
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