A concise synthesis of 3-deoxy-2-O-methyl-4,5,7-tri-O-benzyl-D-arabino-heptulosonic acid and related compounds from 3,4,6-tri-O-benzyl-D-glucal
Abstract
A concise, de novo synthesis of the 3-deoxyulosonic acid glycosyl donors (14) and (15) from trio-O-benzyl-D-glucal and their transformation into the corresponding O-methyl glycosides is described.