Issue 13, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Spontaneous oxidation of water to oxygen by the mixed-valence µ-oxo ruthenium dimer L2(H2O)RuIII–O–RuIV(OH)L2(L = 2,2′-bipyridyl-5,5′-dicarboxylic acid)

Mohammad K. Nazeeruddin,   François P. Rotzinger,   Pascal Comte  and  Michael Grätzel  

Abstract

The mixed-valence µ-oxo ruthenium dimer L2(H2O)RuIII–O–RuIV(OH)L2, where L = 2,2′-bipyridyl-5,5′-dicarboxylic acid, converts spontaneously into L2(H2O)RuIII–O–RuIII(H2O)L2 under simultaneous oxidation of water to oxygen under conditions where the driving force of the reaction is less than 0.1 eV per transferred electron.

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Article information

DOI
https://doi.org/10.1039/C39880000872
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 872-874

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Spontaneous oxidation of water to oxygen by the mixed-valence µ-oxo ruthenium dimer L2(H2O)RuIII–O–RuIV(OH)L2(L = 2,2′-bipyridyl-5,5′-dicarboxylic acid)

M. K. Nazeeruddin, F. P. Rotzinger, P. Comte and M. Grätzel, J. Chem. Soc., Chem. Commun., 1988, 872 DOI: 10.1039/C39880000872

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