A new method for regiospecific C–C coupling of terminal alkenes based on a sulphonylation–alkylation–desulphinylation process, mediated through allylic sulphinic acids, and its application to the conversion of limonene into E- and Z-α-bisabolenes, are described.
J. E. Baldwin, R. M. Adlington, Y. Ichikawa and C. J. Kneale, J. Chem. Soc., Chem. Commun., 1988, 702 DOI: 10.1039/C39880000702
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