Issue 9, 1988

Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S4] to [(η5-C5Me5)2Fe2S4](PF6)2

Abstract

Electrochemical oxidation of [(η5-C5Me5)2Fe2S4] in MeCN containing NH4PF6 affords [(η5-C5Me5)2Fe2S4](PF6)2 in which a bidentate µ-S2 ligand in the parent complex is converted to a doubly bidentate µ-S2 ligand; the structure of the resulting Fe2S4 core can be described as a distorted octahedron, as shown by an X-ray crystal structure determination.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 586-587

Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S4] to [(η5-C5Me5)2Fe2S4](PF6)2

H. Ogino, H. Tobita, S. Inomata and M. Shimoi, J. Chem. Soc., Chem. Commun., 1988, 586 DOI: 10.1039/C39880000586

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