A formal synthesis of the Inhoffen–Lythgoe diol (1) featuring a novel intermolecular Diels–Alder strategy wherein an intact C(20) stereocentre as part of a diene unit is used to elaborate directly the stereocentres at C(13) and C(17) of the hydrindan ring system of (1), is reported.
E. Brandes, P. A. Grieco and P. Garner, J. Chem. Soc., Chem. Commun., 1988, 500 DOI: 10.1039/C39880000500
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