SCHEDULED MAINTENANCE
[(η5-C5H5)Mo(CO)3]2(1) reacts with grey arsenic in boiling water-saturated toluene to produce the new trioxocluster [µ3-As(µ-O)3{(η5-C5H5)Mo}3](3), while reaction of As4S4, (1), and grey arsenic under the same conditions yields [µ3-As(µ-O)2(µ-S){(η5-C5H5)Mo}3](4); X-ray structure analyses were performed for both products.
H. Neumann and M. L. Ziegler, J. Chem. Soc., Chem. Commun., 1988, 498 DOI: 10.1039/C39880000498
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