The remarkably facile SRN 1 reaction of 4-tricyclyl iodide and the near inertia of 4-tricyclyl chloride under the same conditions are compared with the reactivity of other bridgehead compounds; the nature of the SRN 1 reaction for aliphatic substrates is discussed.
A. N. Santiago, D. G. Morris and R. A. Rossi, J. Chem. Soc., Chem. Commun., 1988, 220 DOI: 10.1039/C39880000220
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