SCHEDULED MAINTENANCE
Ab initio calculations at the HF/6-31G*(and in some cases MP2/6-31G*)//3-21G(*) level on H4-nSi(OH)n(n= 0–4) species show that significant anomeric (negative hyperconjugation) stabilizations occur at silicon centres; in contrast, π-bonding with silicon 3d orbitals is a minor effect.
A. E. Reed, C. Schade, P. von Ragué Schleyer, P. V. Kamath and J. Chandrasekhar, J. Chem. Soc., Chem. Commun., 1988, 67 DOI: 10.1039/C39880000067
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