A mixture of iodine and CuO·HBF4 reacts stereospecifically with olefins in the presence of a wide variety of nucleophiles (NaNO2, NaSO2Ar, Nal, Et3SiH, MeOPh and H2O) to give the corresponding 2-functionalized iodo compounds; the same reagents also cause iodofunctionalization of 1,3-dienes and acetylenes.
J. Barluenga, M. A. Rodríguez, P. J. Campos and G. Asensio, J. Chem. Soc., Chem. Commun., 1987, 1491 DOI: 10.1039/C39870001491
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