Issue 14, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Convenient synthesis of 4-nitrotetralones by selective side-chain nitration of methyl-substituted acryloylbenzenes, followed by intramolecular Michael reaction

Takashi Keumi,   Toshihiko Inagaki,   Norihiro Nakayama,   Toshio Morita  and  Hidehiko Kitajima  

Abstract

Reaction of polymethyl-substituted acryloylbenzenes (1) with fuming nitric acid in acetic anhydride gave the products (2) derived from selective side-chain nitration at the ortho-position; the subsequent intramolecular Michael reaction leads to exclusive formation of 4-nitrotetralones (3).

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Article information

DOI
https://doi.org/10.1039/C39870001091
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1091-1092

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Convenient synthesis of 4-nitrotetralones by selective side-chain nitration of methyl-substituted acryloylbenzenes, followed by intramolecular Michael reaction

T. Keumi, T. Inagaki, N. Nakayama, T. Morita and H. Kitajima, J. Chem. Soc., Chem. Commun., 1987, 1091 DOI: 10.1039/C39870001091

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