Issue 13, 1987

Stereoselective total synthesis of (S)-(–)-dolichol-20

Abstract

A stereoselective synthesis of (S)-(–)-dolichol-20 (1a) was achieved using (Z,Z,Z,Z,Z,Z,Z,Z,E,E)-undercaprenol (11), the C20 block (5), and the optically active C25 block (3) as the key building blocks.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1036-1037

Stereoselective total synthesis of (S)-(–)-dolichol-20

S. Inoue, T. Kaneko, Y. Takahashi, O. Miyamoto and K. Sato, J. Chem. Soc., Chem. Commun., 1987, 1036 DOI: 10.1039/C39870001036

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