Issue 13, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Phosphine complexes of main group elements. A bis-phosphinomethyl lithiate as an anionic diphosphine ligand to lithium: synthesis and structure of {[Me2N(CH2)2NMe2]Li[(Me2P)C(SiMe3)2]2Li}

Hans H. Karsch,   Armin Appelt,   Brigitte Deubelly  and  Gerhard Müller  

Abstract

A novel type of Li complexation has been established by X-ray crystallography for the title compound revealing two distinctly different Li atoms, whereas the related compelxes {(thf)Li[(Me2P)2CX]}2(X = SiMe3, PMe2·, thf = tetrahydrofuran) feature equivalent environments for both lithium atoms.

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Article information

DOI
https://doi.org/10.1039/C39870001033
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1033-1034

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Phosphine complexes of main group elements. A bis-phosphinomethyl lithiate as an anionic diphosphine ligand to lithium: synthesis and structure of {[Me2N(CH2)2NMe2]Li[(Me2P)C(SiMe3)2]2Li}

H. H. Karsch, A. Appelt, B. Deubelly and G. Müller, J. Chem. Soc., Chem. Commun., 1987, 1033 DOI: 10.1039/C39870001033

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