Issue 12, 1987

Selective oxidations with activated carbon: applications to substrates containing acidic allytic methine and methylene groups

Abstract

Butenoates substituted at the γ-position with an acidifying group, e.g., COR, CO2R, SO2R, and PO(OR)2, undergo a regioselective oxidation (in which a methine group is converted into a carbinol function and a methylene group into a keto moiety) in the presence of activated carbon.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 882-883

Selective oxidations with activated carbon: applications to substrates containing acidic allytic methine and methylene groups

G. D. S. Ananda, P. J. Cremins and R. J. Stoodley, J. Chem. Soc., Chem. Commun., 1987, 882 DOI: 10.1039/C39870000882

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