Whereas selenoxide elimination from the hydroxyselenide (6) gave predominantly exocyclic elimination, preferred endocyclic elimination was observed from the corresponding ketone (5), and was applied to a synthesis of the cyclohexenediol fragment of the non-aromatic β-milbemycins.
S. V. Mortlock, N. A. Stacey and E. J. Thomas, J. Chem. Soc., Chem. Commun., 1987, 880 DOI: 10.1039/C39870000880
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