Issue 11, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray crystal structure of [(C5Me5)2Sm]2C4Ph2, a samarium η2-complex derived from an alkyne

William J. Evans,   Roy A. Keyer,   Hongming Zhang  and  Jerry L. Atwood  

Abstract

(C5Me5)2Sm(thf)2(thf = tetrahydrofuran) reacts with PhC[triple bond, length half m-dash]CC[triple bond, length half m-dash]CPh to form [(C5Me5)2Sm]2C4Ph2 which is found by X-ray crystallography to have η2-co-ordination of Sm3+ to the carbon–carbon multiple bonds.

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Article information

DOI
https://doi.org/10.1039/C39870000837
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 837-838

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Synthesis and X-ray crystal structure of [(C5Me5)2Sm]2C4Ph2, a samarium η2-complex derived from an alkyne

W. J. Evans, R. A. Keyer, H. Zhang and J. L. Atwood, J. Chem. Soc., Chem. Commun., 1987, 837 DOI: 10.1039/C39870000837

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