The synthesis, stereochemistry, mechanisms of formation, and X-ray crystal structures of enantiomerically pure π-allylpalladium compounds (1)–(3) prepared by palladium hydride addition to (1R)-(+)-α-pinene, (1S)-(–)-α- or -β-pinene, and (1S)-(+)-2- or -3-carene respectively are presented.
R. C. Larock, H. Song, S. Kim and R. A. Jacobson, J. Chem. Soc., Chem. Commun., 1987, 834 DOI: 10.1039/C39870000834
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