Reaction between [(η6-C6Me6)RuCl2]2 and K[B6H11] yields a rare example of a 2-metalla nido-decaborane derivative, [2-(η6-C6Me6)-nido-2RuB9H 13], together with an unprecedented 1-ruthena isomer having the same empirical formula but a more open arachno-type structure.
M. Bown, X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy and P. MacKinnon, J. Chem. Soc., Chem. Commun., 1987, 817 DOI: 10.1039/C39870000817
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