The synthesis, structure, and magnetic properties of [Mn4O2(OAc)7(bipy)2](ClO4)·3H2O, bipy = 2,2′-bipyridine) are reported; this complex is the first tetranuclear oxide-bridged manganese(III) species and represents the best available model for the photosynthetic water oxidation centre.
J. B. Vincent, C. Christmas, J. C. Huffman, G. Christou, H. Chang and D. N. Hendrickson, J. Chem. Soc., Chem. Commun., 1987, 236 DOI: 10.1039/C39870000236
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