Treatment of [PtCl2PCH2PPh2-P,P′)] with an excess of NaOH in NH3 at –50 °C gives, in >80% yield, the cis and trans isomers of [(Ph2MeP)(Ph2PO)Pt(µ-NH2)2Pt((POPh2)(PMePh2)], the structure of the trans from being confirmed by X-ray crysallography; both the structure and the proposed mechanism display highly novel features.
N. W. Alcock, P. Bergamini, T. J. Kemp and P. G. Pringle, J. Chem. Soc., Chem. Commun., 1987, 235 DOI: 10.1039/C39870000235
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