Issue 2, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

The chemistry of dinitrogen residues. Part 2. Organohydrazido(1–)-derivatives of titanium(IV). X-Ray crystal structures of [Ti(C5H5)Cl2(NPhNH2)] and [Ti(C5H5)Cl2(NHNMe2)]

Ian A. Latham,   G. Jeffery Leigh,   Gottfried Huttner  and  Ibrahim Jibril  

Abstract

The structures of [Ti(C5H5)Cl2(NPhNH2)] and [Ti(C5H5)Cl2(NHNMe2)] are described. Both contain side-on hydrazide(1–) fragments with N–N single bonds but an asymmetric TiNN unit. These compounds, and several other homologues, react with protic acids to generate the hydrazine.

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Article information

DOI
https://doi.org/10.1039/DT9860000385
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 385-391

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The chemistry of dinitrogen residues. Part 2. Organohydrazido(1–)-derivatives of titanium(IV). X-Ray crystal structures of [Ti(C5H5)Cl2(NPhNH2)] and [Ti(C5H5)Cl2(NHNMe2)]

I. A. Latham, G. J. Leigh, G. Huttner and I. Jibril, J. Chem. Soc., Dalton Trans., 1986, 385 DOI: 10.1039/DT9860000385

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