The chemistry of dinitrogen residues. Part 1. Diazenido-complexes of titanium, and some substituted analogues. X-Ray crystal structures of [Ti(C5H5)Cl2(NNPh)], [Ti(C5H5)Cl2(NCBunBut)], and [Ti(C5H5)Cl2(NPPh3)]

Ian A. Latham; G. Jeffery Leigh; Gottfried Huttner; Ibrahim Jibril

doi:10.1039/DT9860000377

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The chemistry of dinitrogen residues. Part 1. Diazenido-complexes of titanium, and some substituted analogues. X-Ray crystal structures of [Ti(C₅H₅)Cl₂(NNPh)], [Ti(C₅H₅)Cl₂(NCBuⁿBu^t)], and [Ti(C₅H₅)Cl₂(NPPh₃)]

Ian A. Latham, G. Jeffery Leigh, Gottfried Huttner and Ibrahim Jibril

Abstract

The structures of [Ti(C₅H₅)Cl₂(NCBuⁿBu^t)], [Ti(C₅H₅)Cl₂(NPPh₃)], and [Ti(C₅H₅)Cl₂(NNPh)] are described. The first two compounds contain NCBuⁿBu^t and NPPh₃ bound end-on with Ti–N double bonds which are rare. The last contains a unique side-on NNPh group. The NNPh can be removed from the complex as phenylhydrazine upon reaction with acid.

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DOI: https://doi.org/10.1039/DT9860000377
Article type: Paper

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J. Chem. Soc., Dalton Trans., 1986, 377-383

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The chemistry of dinitrogen residues. Part 1. Diazenido-complexes of titanium, and some substituted analogues. X-Ray crystal structures of [Ti(C₅H₅)Cl₂(NNPh)], [Ti(C₅H₅)Cl₂(NCBuⁿBu^t)], and [Ti(C₅H₅)Cl₂(NPPh₃)]

I. A. Latham, G. J. Leigh, G. Huttner and I. Jibril, J. Chem. Soc., Dalton Trans., 1986, 377 DOI: 10.1039/DT9860000377

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Journal of the Chemical Society, Dalton Transactions

The chemistry of dinitrogen residues. Part 1. Diazenido-complexes of titanium, and some substituted analogues. X-Ray crystal structures of [Ti(C₅H₅)Cl₂(NNPh)], [Ti(C₅H₅)Cl₂(NCBuⁿBu^t)], and [Ti(C₅H₅)Cl₂(NPPh₃)]

Abstract

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The chemistry of dinitrogen residues. Part 1. Diazenido-complexes of titanium, and some substituted analogues. X-Ray crystal structures of [Ti(C₅H₅)Cl₂(NNPh)], [Ti(C₅H₅)Cl₂(NCBuⁿBu^t)], and [Ti(C₅H₅)Cl₂(NPPh₃)]

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