Issue 24, 1986

Screw sense selective polymerization of achiral lsocyanides catalysed by complexes of nickel(II) and optically active amines

Abstract

Polymerization of t-butyl and t-pentyl isocyanide by nickel(II) in the presence of optically active amines yields helical polymers with an enantiomeric excess of up to 61%.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1789-1791

Screw sense selective polymerization of achiral lsocyanides catalysed by complexes of nickel(II) and optically active amines

P. C. J. Kamer, R. J. M. Nolte and W. Drenth, J. Chem. Soc., Chem. Commun., 1986, 1789 DOI: 10.1039/C39860001789

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