Issue 24, 1986

Diels–Alder reactions in hydrophobic cavities: a quantitative correlation with solvophobicity and rate enhancements by macrocycles

Abstract

Based on the reaction of cyclopentadiene with diethyl fumarate a linear correlation of log k vs. solvophobicity parameters is reported as well as saturation kinetics showing up to 70-fold rate increase by complexation in β-cyclodextrin.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1787-1789

Diels–Alder reactions in hydrophobic cavities: a quantitative correlation with solvophobicity and rate enhancements by macrocycles

H. Schneider and N. K. Sangwan, J. Chem. Soc., Chem. Commun., 1986, 1787 DOI: 10.1039/C39860001787

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements