SCHEDULED MAINTENANCE
2-Aryloxy-1,3,2-dioxaphospholanes break down on pyrolysis in the gas phase by a mechanism best accounted for in terms of the formation of metaphosphate (ArOPO2) moieties, which rearrange to cyclic phosphonic monoesters via intramolecular insertion reactions, unless an abstractable β-hydrogen is present when a Chugaev-type reaction takes place to give a terminal alkene.
J. I. G. Cadogan, A. H. Cowley, I. Gosney, M. Pakulski, P. M. Wright and S. Yaslak, J. Chem. Soc., Chem. Commun., 1986, 1685 DOI: 10.1039/C39860001685
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