Reaction between the resolved iridium enamide complex (+)-(3) or (–)-(3) and chiral biphosphines is highly enantioselective and permits their in situ resolution for asymmetric catalysis; the structure of (+)-(3) has been confirmed by X-ray crystallography.
N. W. Alcock, J. M. Brown and P. J. Maddox, J. Chem. Soc., Chem. Commun., 1986, 1532 DOI: 10.1039/C39860001532
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