Issue 20, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Spontaneous self assembly of the {M2(µ-O)(µ-MeCO2)2}2+ core. Synthesis, structure, and properties of the binuclear vanadium(III) complex

Karl Wieghardt,   Martin Köppen,   Bernhard Nuber  and  Johannes Weiss  

Abstract

The green complex [L2V2(µ-O)(µ-MeCO2)2]I2·2H2O, where L represents N,N′,N″-trimethyl-1,4,7-triazacyclononane, is formed spontaneously on hydrolysis of LVCl3·dmf (dmf = dimethylformamide) in water in the presence of sodium acetate; characterization by X-ray crystallography showed the presence of the µ-oxo-di-µ-acetato-divanadium(III) core.

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Article information

DOI
https://doi.org/10.1039/C39860001530
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1530-1532

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Spontaneous self assembly of the {M2(µ-O)(µ-MeCO2)2}2+ core. Synthesis, structure, and properties of the binuclear vanadium(III) complex

K. Wieghardt, M. Köppen, B. Nuber and J. Weiss, J. Chem. Soc., Chem. Commun., 1986, 1530 DOI: 10.1039/C39860001530

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