In the presence of ammonia, β-methylaspartase catalyses the conversion of halogenofumaric acids into the corresponding β-halogenoaspartic acids; one of the products, bromoaspartic acid, is an irreversible inhibitor.
M. Akhtar, M. A. Cohen and D. Gani, J. Chem. Soc., Chem. Commun., 1986, 1290 DOI: 10.1039/C39860001290
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