Issue 12, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Oxidation intermediates of borohydride and tetraphenylborate ions in aqueous solutions obtained by pulse radiolysis

Hideo Horii  and  Setsuo Taniguchi  

Abstract

Absorption spectra of one-electron oxidized intermediates (the H4B· and the Ph4B· radicals) were observed upon the oxidation of H4B– and Ph4B– by the azide radical (N3·), Br2[graphic omitted], or (SCN)2[graphic omitted] in plus-irradiated solutions; the spectra have absorption maxima at 400 nm, ε= 1800 dm3 mol–1 for H4B· and at 335 nm, ε= 8600 dm3 mol–1 for cm–1 for Ph4B·.

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Article information

DOI
https://doi.org/10.1039/C39860000915
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 915-916

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Oxidation intermediates of borohydride and tetraphenylborate ions in aqueous solutions obtained by pulse radiolysis

H. Horii and S. Taniguchi, J. Chem. Soc., Chem. Commun., 1986, 915 DOI: 10.1039/C39860000915

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