Various cyclenones have been homologated by a two-step sequence involving a reaction with α-selenoalkyl-lithium compounds and further reaction of the resulting β-hydroxyselenides with thallium(I) ethoxide in chloroform; an unusually high propensity of the alkyl groups to migrate in place of the vinyl moiety has been observed.
A. Krief and J. L. Laboureur, J. Chem. Soc., Chem. Commun., 1986, 702 DOI: 10.1039/C39860000702
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