Issue 9, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

The first example of a µ4-η1,η2-acetylide dianion: preparation and X-ray structure of Ru4(µ4-η1,η2-C2)(µ-PPh2)2(CO)12

Michael I. Bruce,   Michael R. Snow,   Edward R. T. Tiekink  and  Michael L. Williams  

Abstract

Carbonylation of the diphenylphosphinoacetylide complex Ru5(µ5-C2PPh2)(µ-PPh2)(CO)15, (2), results in cleavage of the P–C[triple bond, length half m-dash]C bond and formation of Ru4(µ4-η1,η2-C2)(µ-PPh2)2(CO)12, (3), shown by an X-ray structure to contain the novel η1,η2-acetylide dianion bridging two Ru2(µ-PPh2)(CO)6 units.

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Article information

DOI
https://doi.org/10.1039/C39860000701
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 701-702

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The first example of a µ4-η1,η2-acetylide dianion: preparation and X-ray structure of Ru4(µ4-η1,η2-C2)(µ-PPh2)2(CO)12

M. I. Bruce, M. R. Snow, E. R. T. Tiekink and M. L. Williams, J. Chem. Soc., Chem. Commun., 1986, 701 DOI: 10.1039/C39860000701

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