SCHEDULED MAINTENANCE:
The angularly fused triquinane, (±)-3-oxosilphinene (4), was stereoselectively synthesised via an intramolecular Diels–Alder reaction as the key step.
M. Ihara, A. Kawaguchi, M. Chihiro, K. Fukumoto and T. Kametani, J. Chem. Soc., Chem. Commun., 1986, 671 DOI: 10.1039/C39860000671
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