Issue 9, 1986

Diastereofacial reactivity of (E)-3-trimethylsilyloxybuta-1,3-dien-1-yl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

Abstract

The title diene shows a notable diastereofacial reactivity in cycloadditions with p-benzoquinones, N-phenylmaleimide, and maleic anhydride; the structure of the trione (14) has been determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 668-670

Diastereofacial reactivity of (E)-3-trimethylsilyloxybuta-1,3-dien-1-yl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

R. C. Gupta, A. M. Z. Slawin, R. J. Stoodley and D. J. Williams, J. Chem. Soc., Chem. Commun., 1986, 668 DOI: 10.1039/C39860000668

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