Issue 8, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of a di-iron-µ-vinylidine group from ethylene: synthesis and crystal structure of {MeSi(CH2PMe2)3}Fe(µ-C[double bond, length half m-dash]CH2)(µ-H)2Fe{(PMe2CH2)3SiMe}

James M. Boncella,   Malcolm L. H. Green  and  Dermot O'Hare  

Abstract

Treatment of (η4-C6H6)(tmps)Fe, tmps = MeSi(CH2PMe2)3, with ethylene, or sodium amalgam reduction of (tmps)FeCl2 in the presence of ethylene, gives the di-iron-µ-vinylidene compound (tmps)Fe(µ-C[double bond, length half m-dash]CH2)(µ-H)2Fe(tmps) whose crystal structure has been determined.

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Article information

DOI
https://doi.org/10.1039/C39860000618
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 618-619

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Formation of a di-iron-µ-vinylidine group from ethylene: synthesis and crystal structure of {MeSi(CH2PMe2)3}Fe(µ-C[double bond, length half m-dash]CH2)(µ-H)2Fe{(PMe2CH2)3SiMe}

J. M. Boncella, M. L. H. Green and D. O'Hare, J. Chem. Soc., Chem. Commun., 1986, 618 DOI: 10.1039/C39860000618

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