The formation of the cyclic sulphoxide (R)-(6) by treatment of the bromoarene (R)-(2) with tributylstannane indicates that intramolecular homolytic substitution at the sulphur centre of the sulphoxide group proceeds with strict inversion of configuration.
A. L. J. Beckwith and D. R. Boate, J. Chem. Soc., Chem. Commun., 1986, 189 DOI: 10.1039/C39860000189
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