Issue 3, 1986

The preparation and crystal structure of the unusual copper–sulphur cage complex Cu8(SC5H11)4(S2CSC5H11)4

Abstract

The electrochemical oxidation of anodic copper in an acetonitrile solution of RSH (R = Ph, C10H7, CPh3, C6F4H, o-MeC6H4, CMe2Et) yields CuSR; treatment of CuSCMe2Et with CS2 produces Cu8(SR)4(S2CSR)4, whose structure is based on an unusual Cu8S12 cage.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 188-189

The preparation and crystal structure of the unusual copper–sulphur cage complex Cu8(SC5H11)4(S2CSC5H11)4

R. Chadha, R. Kumar and D. G. Tuck, J. Chem. Soc., Chem. Commun., 1986, 188 DOI: 10.1039/C39860000188

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