Alkali metal cations (K+ and Na+) bound to 18-crown-6 having a pendant thiazolium ion were found to increase the rate of the oxidative decarboxylation of pyruvic acid in EtOH by binding the substrate and acting as the catalytic site.
Y. Yano, M. Kimura, K. Shimaoka and H. Iwasaki, J. Chem. Soc., Chem. Commun., 1986, 160 DOI: 10.1039/C39860000160
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