Discrepancies in recent reports from different laboratories on the i.r. spectrum of matrix-isolated cyclopentadienone O-oxide have now been reconciled by showing that two distinct isomers may be formed from cyclopentadienylidene and O2, and that one, a carbonyl oxide, may be converted photolytically into the other, a dioxirane.
I. R. Dunkin and C. J. Shields, J. Chem. Soc., Chem. Commun., 1986, 154 DOI: 10.1039/C39860000154
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