The compound (NSCl)3 reacts with ruthenium(II) complexes of type [Ru(η5-C5H5)X(PPh3)2](X = Cl, Br, CN, SCN, or SnCl3) and [RuCl2(PPh3)2(pip)2](pip = piperidine) to yield [Ru(NSCl)2X(X′)(PPh3)2](X = Cl; X′= Cl, Br, CN, SCN, or SnCl3) and [Ru(NSCl)2C12(PPh3)(pip)], respectively. The complexes have been characterized by elemental analyses, spectroscopic (i.r.,1H n.m.r., u.v.–visible), magnetic susceptibility, and t.l.c. data.
M. Gupta, R. F. N. Ashok, A. Mishra, V. B. S. Chauhan and U. C. Agarwala, J. Chem. Soc., Dalton Trans., 1985, 2449 DOI: 10.1039/DT9850002449
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