α-Nitrofurans bearing acyl or alkoxycarbonyl groups on the α′-Position undergo cine-substitution of the α-nitro group when treated with the anions of secondary nitroalkanes, whereas with other nucleophiles, normal substitution of the α-nitro group occurs.
B. J. Barnes, P. J. Newcombe, R. K. Norris and K. Wilson, J. Chem. Soc., Chem. Commun., 1985, 1408 DOI: 10.1039/C39850001408
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