The MnII/4,5-dihydroxybenzene-1,3-disulphonate (Tiron) system catalyses the production of hydrogen peroxide from dioxygen and hydroxylamine in the pH range 7.5–8.6; concentrations of hydrogen peroxide >0.2 mol dm–3 and turnover numbers [H2O2]/[MnII] > 104 can be obtained.
D. F. Evans and T. S. Sheriff, J. Chem. Soc., Chem. Commun., 1985, 1407 DOI: 10.1039/C39850001407
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