The observation of four bond, extended ‘W’ pathway, 1H, 1H connectivities between specific protons of the methylene and methyl groups in methyl methacrylate oligomers (1)–(6) by 1H n.m.r. 2D-correlation spectroscopy indicates preferred conformations in solution for chains composed of methyl methacrylate units.
P. Cacioli, D. G. Hawthorne, S. R. Johns, D. H. Solomon, E. Rizzardo and R. I. Willing, J. Chem. Soc., Chem. Commun., 1985, 1355 DOI: 10.1039/C39850001355
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