The bonding in high nuclearity clusters with close packed arrangements of metal atoms is dependent primarily on the radial interactions between the surface and interstitial atoms; these clusters are characterised by 12ns+Δi valence electrons, where ns is the number of surface atoms and Δi is a characteristic of the interstitial group of atoms.
D. M. P. Mingos, J. Chem. Soc., Chem. Commun., 1985, 1352 DOI: 10.1039/C39850001352
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