The volume for outer-sphere electron transfer between Co(terpy)22+ and Co(bpy)33+(terpy = 2,2′,6′,2″-terpyridiene, bpy = 2,2′-bipyridine) in dilute aqueous solution (–9 ± 1 cm3 mol–-1 at 25 °C and ionic strength 0.01 M) is close to that predicted by the conventional Hush–Marcus theories.
P. Braun and R. van Eldik, J. Chem. Soc., Chem. Commun., 1985, 1349 DOI: 10.1039/C39850001349
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