The reaction of Ru3(CO)12 with 2,2′-bipyridine (bipy) in hexane gives in high yield Ru3(CO)10(bipy), containing two asymmetrically bridging carbonyl groups trans-to the perpendicularly co-ordinated bipyridine ligand.
T. Venäläinen, J. Pursiainen and T. A. Pakkanen, J. Chem. Soc., Chem. Commun., 1985, 1348 DOI: 10.1039/C39850001348
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