Poly(3-substituted Thiophene-2,5-diyls) incorporating co-ordinated transition metals have been shown to exhibit a dramatic increase in conductivity on ‘doping’ with water from 10–8 to greater than 10–1 S cm–1; however, only the polymer containing CuII exhibits electronic conduction and internal electrochemical redox waves.
A. Czerwinski, H. Zimmer, A. Amer, C. van Pham, S. Pons and H. B. Mark, J. Chem. Soc., Chem. Commun., 1985, 1158 DOI: 10.1039/C39850001158
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