The protonated macrocyclic polyamine [24]-N6O2(1) catalyses acetylphosphate hydrolysis and pyrophosphate formation via generation of a phosphorylated intermediate (2) which transfers a phosphoryl group to a phosphate substrate, thus acting as a bond-forming molecular cocatalyst.
M. W. Hosseini and J.-M. Lehn, J. Chem. Soc., Chem. Commun., 1985, 1155 DOI: 10.1039/C39850001155
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